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Rules for obtaining the symmetries of a direct product can be found in texts on character tables. The Laporte rule is a selection rule formally stated as follows: In a centrosymmetric environment, transitions between like atomic orbitals such as s - s , p - p , d - d , or f - f, transitions are forbidden.

The Laporte rule law applies to electric dipole transitions , so the operator has u symmetry meaning ungerade , odd. The transitions are therefore forbidden.

The wave function of a single electron is the product of a space-dependent wave function and a spin wave function. Spin is directional and can be said to have odd parity.

It follows that transitions in which the spin "direction" changes are forbidden. In formal terms, only states with the same total spin quantum number are "spin-allowed".

Both can be observed, in spite of the Laporte rule, because the actual transitions are coupled to vibrations that are anti-symmetric and have the same symmetry as the dipole moment operator.

In vibrational spectroscopy, transitions are observed between different vibrational states. The symmetry of the ground-state wave function is the same as that of the molecule.

It is, therefore, a basis for the totally symmetric representation in the point group of the molecule. It follows that, for a vibrational transition to be allowed, the symmetry of the excited state wave function must be the same as the symmetry of the transition moment operator.

The excited state wave function must also transform as at least one of these vectors. In Raman spectroscopy , the operator transforms as one of the second-order terms in the right-most column of the character table, below.

The molecule methane, CH 4 , may be used as an example to illustrate the application of these principles. Geschlecht Bitte auswählen Pro Person sind maximal 2 Accounts erlaubt.

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If you cannot use Bittorrent, some spins offer alternative download methods. Learn more. Spins are provided as ISO files.

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